Villarreal visit Barcelona on Tuesday at Camp Nou. where they have lost on their last eight visits and not won for over a decade.
Last season they lost 2-0 with goals from Gerard Pique and Carles Alena. The Barca team was: Ter Stegen, Semedo, Piqué, Lenglet, Jordi Alba, Busquets, Rakitic, Arturo Vidal (Aleñà), Dembélé, Messi and Coutinho (Malcom).
Villarreal's team was: Asenjo, Mario, Álvaro, Víctor Ruiz, Pedraza, Cáseres, Trigueros (Bacca), Cazorla (Raba), Fornals, Chukweueze, Gerard Moreno (Toko Ekambi).
They last won there in the 2007-08 season, with Jon Tomasson's goal handing them a 2-1 win 10 mins from the end.
Villarreal's overall balance at Camp Nou is three wins, four draws and 12 defeats, with 47 goals for the hosts and 21 for the visitors.